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Earth Science Laboratories, Inc.
103 SE 22nd Street, Suite 1
Bentonville, AR 72712
Emergency Phone Number: 1-800-535-5053 (Infotrac)
Information Phone Number: 1-479-271-7381
www.earthsciencelabs.com
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Material Name: EarthTec®
Issue Date: 12/93
Revision Date: 7/03
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Section 1 – PRODUCT IDENTIFICATION
Product Name: EarthTec® EPA No: 64962-1
Section 2 – HAZARDOUS INGREDIENTS
Components CAS # OSHA PEL ACGIH TLV %
Copper sulfate pentahydrate 7758-99-8 1 mg/m3 1 mg/m3
18.25-21.75%
Section 3 – HEALTH HAZARDS IDENTIFICATION
Primary Routes of Entry: Inhalation, Absorption, and
Ingestion.
Eyes: Corrosive. Exposure may cause severe burns,
destruction of eye tissue and possible permanent injury or
blindness.
Skin: Corrosive. Contact may cause reddening, itching,
inflammation, burns, blistering and possibly tissue damage.
Ingestion: Corrosive. May cause painful irritation and
burning of the mouth and throat, painful swallowing, labored
breathing, burns or perforation of the gastrointestinal
tract leading to ulceration and secondary infection.
Inhalation: Irritating. Overexposure may cause burns and
tissue damage.
Section 4 – FIRST AID MEASURES
Eyes: Flush immediately with large amounts of water for at
least 20 minutes. Eyelids should be held away from the
eyeball to ensure thorough rinsing. Get immediate medical
attention.
Skin: Immediately flush skin with plenty of water for at
least 20 minutes while removing contaminated clothing and
shoes. Get immediate medical attention.
Ingestion: If victim is conscious and alert, give 1-3
glasses of water to dilute stomach contents. Rinse mouth out
with water. Do not induce vomiting unless directed by
medical personnel. Get immediate medical attention.
Inhalation: Remove to fresh air. If not breathing, institute
cardiopulmonary resuscitation (CPR). If breathing is
difficult, ensure clear airway and give oxygen. Keep
affected person warm and at rest. Get immediate medical
attention.
Section 5 – FIRE AND EXPLOSION HAZARDS
Flash Point: N/E UFL: N/E LFL: N/E
General Fire Hazards: Water applied directly could result in
spattering of acid solution.
Hazardous Combustion Products: May react with high carbon
metals to produce hydrogen gas, which can form an explosive
mixture.
Fire Fighting Equipment/Instructions: Firefighters must wear
MSHA/NIOSH approved positive pressure breathing apparatus (SCBA)
with full face mask and full protective equipment.
NFPA Ratings: Fire: 0 Health: 2 Reactivity: 1 Other: X
HMIS III Ratings: Fire: 0 Health: 2 Reactivity: 1 Personal
Protection: X
Section 6 – ACCIDENTAL RELEASE MEASURES
Containment Procedures: Flush with water into retaining area
or container. Caution should be exercised regarding personal
safety and exposure to released product.
Clean-Up Procedures: Neutralize solution with bicarbonate of
soda.
Evacuation Procedures: Keep unnecessary people away; isolate
hazard area and deny entry. Stay upwind.
Special Instructions: Notify local authorities and the
National Response Center, if required.
Section 7 – HANDLING AND STORAGE
Procedures for Handling: Avoid contact with strong
oxidizers. Do not use with materials or equipment sensitive
to corrosive solutions.
Recommended Storage Methods: Avoid storage in excessive
heat; expansion of container may occur creating spillage. Do
not store in galvanized or nylon equipment.
Section 8 – PERSONAL PROTECTION
Respiratory Protection: Ventilation and other forms of
engineering controls are the preferred means for controlling
exposures. A NIOSH/ MSHA approved air-purifying respirator
with an appropriate acid gas cartridge or canister may be
appropriate under certain circumstances where airborne
concentrations are expected to exceed exposure limits.
Protective Gloves: Use appropriate chemical gloves that are
in usable order.
Other Protective Clothing or Equipment: Eye and face
protection is necessary, long sleeved shirts, long pants,
socks and shoes.
Work/Hygienic Practices: Use good personal hygiene. Body
shower for prolonged skin contact.
Section 9 – PHYSICAL & CHEMICAL PROPERTIES
Appearance: Clear blue liquid
Odor: Minimal odor
Physical State: Liquid
Vapor Density (Air=1): 1.0
PH: 1.0
Evaporation Rate: N/A
Vapor Pressure: 0.1mm 68º F
Solubility in Water: Complete
Boiling Point: 220º F
Specific Gravity (H20=1): 1.2
Melting Point: N/A
Section 10 – REACTIVITY INFORMATION
Chemical Stability: Stable.
Conditions to Avoid: Avoid mixing with strong bases and
strong reducing agents.
Incompatibility: Incompatible with strong bases and strong
reducing agents.
Hazardous Decomposition Products: Sulfur dioxide and sulfur
trioxide may be produced with decomposition.
Hazardous Polymerization: Will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
Acute Toxicity / Chronic Toxicity: Continued overexposure to
this solution may cause systemic toxicity.
Carcinogenicity: N/A
Signs and Symptoms of Exposure: Overexposure may cause the
following specific symptoms, depending on the concentration
and duration of exposure: vomiting, shallow respiration and
lung function changes.
Section 12 – DISPOSAL CONSIDERATIONS
Disposal Instructions: Neutralize with bicarbonate of soda
or fertilizer grade lime and dispose of in accordance with
all federal, state and local regulations.
Section 13 – TRANSPORTATION INFORMATION
DOT Information
Proper Shipping Name: Corrosive liquid, acidic, inorganic,
n.o.s., (contains cupric sulfate)
Hazard Class: 8
UN/NA #: UN3264
Packing Group: III
Packages that contain more than 5.1 US gallons are RQ
(reportable quantity)
Packages that contain less than 4.0 liters could be OMR-D
The proper shipping information is the responsibility of the
shipper and this information is only guidelines.
The information set forth herein is furnished free of charge
and is based on technical data that Earth Science
Laboratories, Inc. believes to be reliable. It is intended
for use by persons having technical skill and at their own
discretion and risk. Since conditions of use are outside our
control, we make no warranties, express or implied, and
assume no liability in connection with any use of the
information. Nothing herein is to be taken as a license to
operate under or a recommendation to infringe any patents.
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